When too
    much of a star's hydrogen has combined to form helium, the star begins to collapse. The
    collapsing star has enough heat to fuse the helium atoms together into elements like carbon (and
    oxygen, if carbon fuses to helium). Depending on the size of the star, these new atoms can
    continue fusing to form elements with even heavier nuclei.
In white dwarf
    stars, the core is all that's left, and the main thing present in that core is helium. If the
    star was larger to begin with, it never forms a white dwarf. Instead, it continues fusion and
    creates heavier elements (the heaviest of which is iron). 
Once iron has been
    fused, there's not much left for the star to do no matter how hot its core may be. It can either
    form a supernova or a black hole.
All the helium that exists in our universe
    comes from this type of fusion.
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